The initial vanadium concentration in the aqueous phase can induce the changes in the vanadium extraction efficiency. Kasikov et al. [45] have reported a sharp decrease in the extraction of vanadium from a solution with pH 2.5, when the initial V(V) concentration increased from 500 mg/l to 2000 mg/l. They have attributed that reduction …

Vanadium chemicals, known as the "vitamins of the modern industry," are major resources widely used in the petroleum, steel, batteries and catalyst industry. Vanadium is also essential in biological systems. Here we review vanadium properties, mineral sources and recovery methods such as blank, sodium and calcium roasting, …

The recovery of vanadium from sulfate leaching solutions is crucial for resource sustainability and environmental protection. However, the leaching solution contains impurities such as Fe (III), which have a significant impact on the separation and enrichment of V because a) the separation of Fe (III) and V (IV) through solvent …

In order to extract vanadium in vanadium slag, the vanadium extraction technologies from the variation of the valence state of vanadium are divided into three categories: …

Separation of vanadium, tungsten and molybdenum from spent SCR catalysts solution by solvent extraction with primary amine N1923 ... little pollution, and simple fabrication. In the literatures, many extractants have been reported to have good extraction separation for the two of three metals V, Mo, and W (Cao et al., 2021, Le …

At present, sodium salt roasting is the most commonly used technology for vanadium extraction from ordinary vanadium slag with lower chromium, [ 8] which includes the …

Effect of Extractants and Initial pH. The extractants used for the recovery of tungsten and vanadium mainly include Aliquat 336, TOA, N1923, and N235 the effect of the four extractants and initial pH on extraction of vanadium and tungsten were depicted in Fig. 1.Among the four extractants, only Aliquat 336 showed high selectivity in the …

The solvent extraction behaviour of vanadium(V) from hydrochloric acid solutions has been investigated using 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (EHEHPA=HX) in kerosene as an extractant. For comparison, extraction studies have also been carried out with vanadium(IV). The results demonstrate that the extraction of …

The extraction efficiency of vanadium remained more than 75% with the increase of the pH value, which can realize the selective extraction and separation of vanadium by using N1923 from iron, aluminum, calcium, sodium, and potassium in …

Stone coal; vanadium; leaching; separation; extraction Introduction Vanadium is an important by-product that is used almost exclusively in ferrous and non-ferrous alloys due to its physical properties such as tensile strength, hardness, and fatigue resistance (Moskalyk and Alfan-tazi 2003). China is rich in mineral resources of

The extraction of vanadium was maximum at pH 2.8, 41.5 °C, and 7.8 × 10 −4 M concentration of aqueous vanadium. The ammine extractant Aliquat 336 has also been extensively used by different authors for extraction of vanadium. The extraction of vanadium from both acidic and alkaline media was studied with Aliquat 336 [11]. The …

New extractant and an extractant system are attractive for liquid-liquid extraction. To improve the extraction efficiency and selectivity, the binary extractant system consisting of bis-2-ethylhexyl phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic mono-2-ethylhexyl (PC88A) was explored to separate vanadium …

In this work, the separation of vanadium(V) from chromium(VI) by pure tricaprylmethylammonium nitrate ([A336] ... Due to the solubilization of IL for the ionic species, the extraction and separation performance of V(V) and Cr(VI) should be enhanced. Hence, it can be expected that the novel IL-based extraction system …

Green separation and efficient extraction of vanadium and chromium from vanadium-chromium leaching solution are serious challenges for the utilization of chrome …

A two-stage extraction process was proposed to recover sulfuric acid and vanadium from simulated acid solution and titanium dioxide waste acid (TDWA). Some extractants were compared and studied, in which the enthalpy changes (ΔH) of the extraction process and the extracted complex were analyzed by using thermodynamics. …

Vanadium products include three grades, vanadium slag and other vanadium extraction raw materials are primary vanadium products, vanadium oxides such as V 2 O 3, V 2 O 5 are secondary vanadium products, and alloys such as Fe V, Al V and metallic vanadium are tertiary vanadium products [20].At present, there have been …

The synergistic extraction mechanism was analyzed by slope method, and stripping experiment was also conducted. In addition, the characterization of leaching slag and a qualified high-titanium slag was prepared. This paper can provide a new reference for the extraction and separation of valuable metals in vanadium titanomagnetite …

A method of roasting-free vanadium recovery from molten vanadium slag via pure oxygen oxidation-assisted acid leaching was investigated in order to implement efficient and green vanadium recovery. The oxidation process of molten vanadium slag discharged from converters by pure oxygen was simulated, and the phase evolution …

Green sucrose reduction-H 2 O 2 selective oxidation route is proposed for selective redox separation of Cr and V.. The difference in redox properties between V and Cr in solution is analyzed. • The optimum parameters on extraction ratio and purity of Cr 2 O 3 and V 2 O 5 products are studied.. High extraction ratios of chromium (96.3%) and vanadium …

Compared with the ion exchange and chemical precipita-tion methods, solvent extraction is a more eficient method for separation and recovery of vanadium. In terms of vanadium …

A H2SO4–H2O2 system was developed to enhance the efficacy of vanadium extraction from roasted vanadium steel slag. The optimum parameters and the behavior of vanadium extraction were investigated systematically. When 1 mL of H2O2 per gram of vanadium slag was added to a leaching mixture at 50 °C, along with 30% H2SO4, 80.5% of …

However, as was shown in Fig. 2, Cyanex 923 may be a suitable extractant candidate for separation of vanadium from iron because Cyanex 923 cannot extract iron (III). Since extraction of Fe (III) by Cyanex 923 was very low based on aqueous solution analysis, as a check the loaded organic solution was also analyzed for mass balance …

Vanadium slag as the product after blast furnace ironmaking and vanadium oxidation in converter with vanadium-bearing titanomagnetite, is a main material for vanadium extraction [[6], [7], [8]]. With the large-scale utilization of the normal vanadium-bearing titanomagnetite with low chromium content, its reserves are decreasing every year.

The extraction and separation of vanadium(IV) and nickel(II) are divided into two stages: acid coleaching of vanadium and nickel and solvent extraction. In the acid coleaching stage, the leaching ...

The vanadium leaching efficiency of 97.23 ± 0.31 pct was obtained under the maximum response conditions predicted by the proposed model. The pure oxygen …

Furthermore, complete separation of vanadium and chromium can be realized, which is difficult to be achieved by sodium roasting-water leaching process (Fu et al., 2020; Wang et al., 2014; Wen et al., 2019b). Hence, calcification roasting process is considered to be a promising vanadium extraction process in the future.

The extraction rate of molybdenum reached 91% and the extraction rate of vanadium was below 18% and the separation factor of both metals was above 47 under the optimal conditions of aqueous pH of ...

At present, the main methods for vanadium separation and concentration are solvent extraction [14] [15] [16] and ion exchange 17,18 . The solvent extraction method, with various extracting ...

An efficient separation and extraction method for the recovery of V (V) from a sulfuric acid leaching solution of vanadium shale was developed using the ionic liquid …

The solvent extraction behavior of vanadium (V) has been investigated using Cyanex 923 [trialkylphosphine oxide (TRPO)] in kerosene as an extractant. For comparison, extraction studies have also been carried out with vanadium (IV). The results demonstrate that vanadium (V) is extracted into the organic phase as VO 2 Cl·TRPO.